» » The Chemistry of Free Radicals: Peroxyl Radicals

Free eBook The Chemistry of Free Radicals: Peroxyl Radicals download

by Zeev B. Alfassi

Free eBook The Chemistry of Free Radicals: Peroxyl Radicals download ISBN: 0471970654
Author: Zeev B. Alfassi
Publisher: Wiley; 1 edition (April 1997)
Language: English
Pages: 546
Category: Engineering & Transportation
Subcategory: Engineering
Size MP3: 1276 mb
Size FLAC: 1403 mb
Rating: 4.2
Format: mbr docx lrf azw


FREE shipping on qualifying offers. title in silver lettering; 1997, John Wiley Publishing; 546 pages; "The Chemistry of Free Radicals: Peroxyl Radicals," by Zeev B. Alfassi. Sold by 1st class books.

FREE shipping on qualifying offers. Peroxy radicals are formed in biological systems, the atmosphere and agueous waste and are important intermediates in the breakdown both of organic molecules and several inorganic species. The implications of their chemistry are far reaching and of great importance. Until now their has been no one volume which bring together all aspects of peroxy radical chemistry - from their formation.

Formation of Peroxyl Radicals in Solution (Z. Alfassi). Methods of Preparing Organic Peroxy Radicals for Laboratory Studies (O. Nielsen & T. Wallington). The Thermochemistry of Peroxides and Polyoxides, and their Free Radicals (S. Benson & N. Cohen)

Formation of Peroxyl Radicals in Solution (Z. Cohen). Ultraviolet Absorption Spectra of Peroxy Radicals in the Gas Phase (O. Kinetic Studies of Organic Peroxyl Radicals in Aqueous Solutions and Mixed Solvents (Z. Alfassi, et a. Electron Spin Resonance Studies of Peroxyl Radicals in Solid Matrices (C. Rhodes)

Peroxyl radicals are formed in biological systems, the atmosphere and aqueous waste and are important intermediates in the breakdown both of organic molecules and several inorganic species

Peroxyl radicals are formed in biological systems, the atmosphere and aqueous waste and are important intermediates in the breakdown both of organic molecules and several inorganic species. As peroxyl radicals react with CFCs and HFCs in the atmosphere resulting in the further destruction of the ozone layer, there has been a great deal of progress towards understanding peroxyl radicals and their reactions in both the gas and liquid phase.

Radicals play a major role as intermediates in many chemical reactions. They contribute to transformations in the atmosphere, living organisms, chemical synthesis, combustion and detonation amongst others. This comprehensive and conclusive book discusses all these aspects. N-centered Radicals deals with NOx and NCO, relatively stable radicals whose presence in the atmosphere influences the metabolism of living organisms. Also included are NHx, NCH and N3, important in radical studies, chemical synthesis, detonation and metabolism.

Items related to The Chemistry of Free Radicals: Peroxyl Radicals. in silver lettering; 1997, John Wiley Publishing; 546 pages; "The Chemistry of Free Radicals: Peroxyl Radicals," by Zeev B. Home The Chemistry of Free Radicals: Peroxyl Radicals. The Chemistry of Free Radicals: Peroxyl Radicals. ISBN 10: 0471970654, ISBN 13: 9780471970651. Bookseller Inventory SKU-T04AP09108125. Ask Seller a Question. Bibliographic Details. Title: The Chemistry of Free Radicals: Peroxyl.

Peroxyl Radicals N-Centered Radicals S-Centered Radicals General Aspects of the Chemistry of Radicals. 5 Combination and Disproportionation of Free Radicals. 139. Zeev B. The chemistry of free radicals. JOHN WILEY & SONS Chichester. New York 5 Combination and Disproportionation of Free Radicals. 6 Radical Ions: Generation, Characterization and Reactions.

In chemistry, a radical is an atom, molecule, or ion that has an unpaired valence electron. With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most organic radicals have short lifetimes. The radicals are of two types- Acid radical and Base radical. A notable example of a radical is the hydroxyl radical (HO,), a molecule that has one unpaired electron on the oxygen atom.

Zeev B. Alfassi, Chien M. Wa. The latter react with oxygen to yield peroxyl radicals. The yields and chemica. More). Wai. 1991. Accurate determination of trace elements is critical in various fields of science and technology. Rate constants for the reactions of several inorganic radicals with several organic reductants in aqueous solutions have been measured by pulse radiolysis as a function of temperature, generall.

During radiolysis in the presence of air peroxyl radicals are important intermediates. For several compounds irradiated in aqueous solution, especially in the case of small alkane-, alkene-and carboxylic acid derived molecules (e. g. methane, cyclopentane, 1,4-cyclohexadiene, acetic acid, hydroxymalonic acid) organic peroxides (mainly hydroperoxides) were found as final products  .

Peroxy radicals are formed in biological systems, the atmosphere and agueous waste and are important intermediates in the breakdown both of organic molecules and several inorganic species. The implications of their chemistry are far reaching and of great importance. Until now their has been no one volume which bring together all aspects of peroxy radical chemistry - from their formation, to their wide and varied chemistry in the aqueous environment, biological systems, solid matrices, polymeric systems and the atmosphere. Peroxy radicals react with CFCs and HFCs in the atmosphere, resulting in the further destruction of the ozone layer - a point which is of topical interest.